日本語

Course Code etc
Academic Year 2023
College College of Science
Course Code automatic registration
Theme・Subtitle
Class Format Face to face (all classes are face-to-face)
Class Format (Supplementary Items)
Campus
Campus Ikebukuro
Semester Spring Semester
DayPeriod・Room Mon.1
ログインして教室を表示する(Log in to view the classrooms.)
Credits 2
Course Number CHE2400
Language Japanese
Class Registration Method Automatic Registration
Assigned Year 配当年次は開講学部のR Guideに掲載している科目表で確認してください。
Prerequisite Regulations
Acceptance of Other Colleges
Course Cancellation
Online Classes Subject to 60-Credit Upper Limit
Relationship with Degree Policy
Notes

【Course Objectives】

A degree from the College of Science is a result of much hard work and study, and is meant to show that a student “understands the fundamental principles, laws, and theory in [their] chosen field, and can apply them as necessary.” In order to make such a statement true, students need to learn the theory behind nuclear magnetic resonance (NMR) spectroscopy, mass spectrometry (MS), infrared spectroscopy (IR), as well as other instrumental analysis methods. Students will need to learn spectral analysis methods, and be able to apply this knowledge to identify the chemical structure of organic compounds from spectral data.

【Course Contents】

In organic chemistry research, being able to determine the chemical structure of reaction products is essential. In this lecture, students will learn the theory behind NMR, MS, IR, and other instrumental analysis methods, as well as how to interpret the spectral data.
After explaining the phenomenon of nuclear magnetic resonance, the necessary information on chemical shifts, integration intensities, spin-spin coupling, and chemical equivalence required to analyze 1H NMR spectra will be explained. Students will then practice how to determine a chemical structure from NMR spectra. 13C NMR will also be discussed, paying particular attention to its similarities and differences compared to 1H NMR, as well as how it can be used as a compliment to 1H NMR.
Following this, the theory behind various ionization methods and ion separation methods will be discussed. Students will then be taught how to interpret mass spectrometry data based on electron-impact ionization.
The course will then move on to IR, whereupon molecular vibrational modes and selection rules will be discussed. Students will then be taught the absorption wavenumbers of various functional groups through real examples, whereupon it will be explained how to interpret IR spectra.
Finally, students will practice identifying the structure of unknown compounds through interpretation of NMR, MS, and IR data.

Japanese Items

【授業計画 / Course Schedule】

1 有機化学における機器分析,NMRの原理
2 1H NMRにおける化学シフト
3 1H NMRにおける積分強度
4 1H NMRにおけるスピン結合
5 1H NMRにおける核の等価性
6 1H NMRスペクトルの帰属
7 13C NMR
8 MS
9 IR
10 各種スペクトルの帰属(1)
11 各種スペクトルの帰属(2)
12 各種スペクトルによる未知化合物の化学構造決定(1)
13 各種スペクトルによる未知化合物の化学構造決定(2)
14 まとめ

【活用される授業方法 / Teaching Methods Used】

板書 /Writing on the Board
スライド(パワーポイント等)の使用 /Slides (PowerPoint, etc.)
上記以外の視聴覚教材の使用 /Audiovisual Materials Other than Those Listed Above
個人発表 /Individual Presentations
グループ発表 /Group Presentations
ディスカッション・ディベート /Discussion/Debate
実技・実習・実験 /Practicum/Experiments/Practical Training
学内の教室外施設の利用 /Use of On-Campus Facilities Outside the Classroom
校外実習・フィールドワーク /Field Work
上記いずれも用いない予定 /None of the above

【授業時間外(予習・復習等)の学修 / Study Required Outside of Class】

授業中に学習した内容を復習する。

【成績評価方法・基準 / Evaluation】

種類 (Kind)割合 (%)基準 (Criteria)
筆記試験 (Written Exam) 80
平常点 (In-class Points)20 授業中に指示する提出物(20%)
備考 (Notes)

【テキスト / Textbooks】

No著者名 (Author/Editor)書籍名 (Title)出版社 (Publisher)出版年 (Date)ISBN/ISSN
1 Silverstein他著,岩澤他訳 『有機化合物のスペクトルによる同定法』第8版 東京化学同人 2016 9784807909162
その他 (Others)
授業中に資料を配付する。

【参考文献 / Readings】

その他 (Others)
必要に応じて授業中に紹介する。

【履修にあたって求められる能力 / Abilities Required to Take the Course】

【学生が準備すべき機器等 / Equipment, etc., that Students Should Prepare】

【その他 / Others】

板書・プリント資料・視覚教材(スクリーン投影)を用いる。
提出物(演習問題など)について授業中に解説し,フィードバックを行う。

【注意事項 / Notice】